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For years, the pair had a heated rivalry in El Clasico - playing against each other a staggering 45 times and always seeming to butt heads.
Ramos put in a number of strong tackles on Messi during their meetings on the pitch and was sent off twice for hacking down Messi.
And so the two becoming teammates after being rivals for so many years was a huge surprise to many - especially when they were all smiles on stage at the Parc Des Princes.
According to L'Equipe, via AS, however, Ramos and Messi haven't patched things up completely.
It's said the two have yet to create a close bond within the PSG dressing room since both joined on free transfers from Barcelona and Real Madrid respectively.
Ramos, despite having yet played for the club due to a calf injury, is believed to have formed a good rapport with a lot of his new colleagues.
Yet he and Messi's relationship is only "cordial" according to the report and the main reason is the fact they were at odds so often over the years.
A source told that L'Equipe that Ramos and Messi “did not erase 10 years of Clásicos from nowhere”.
It was reported that Ramos made a peace offering of sorts to Messi when he told him he could stay with at his house in Paris, though Messi declined the offer.
Messi has played eight times for PSG, while Ramos is still searching for his first outing with the Parisians and is building up his fitness.