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Tonight's highly anticipated game comes to you from the Parc des Princes Stadium in Paris.
Meanwhile, Benfica host Maccabi Haifa in the other game from this group, which we'll provide any key updates on too.
Massimiliano Allegri has rested some key men ahead of a big Serie A match against Bologna, whilst Neymar makes a return for PSG after being left on the bench in his previous outing.
Follow our live coverage of PSG vs Juventus below...
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Thanks for joining us for the coverage of PSG v Juventus in the UEFA Champions League. We'll be back again with a live blog very soon.
Player of the Match: NEYMAR
Although Kylian Mbappe scored the PSG goals, they were laid on a platter by the in-form Brazilian. He epitomised everything good about the Parisians, and even contributed a little pressing from the front towards the end. Sergio Ramos also performed admirably in defence.
Neymar Jr in 2022:— Brasil Football 🇧🇷 (@BrasilEdition) September 6, 2022
Magician 🎩 pic.twitter.com/GRCHZ9NDOp
Benfica will top Group H after beating Maccabi Haifa 2-0. Rafa Silva and Alex Grimaldo ensured last year's quarter finalists got off to a winning start.
A first Champions League win for Christophe Galtier - but plenty to work on for the new boss in the French capital.
FULL-TIME: Three points for PSG. They've showcased why they're one of the favourites for the competition, but also why many think they will falter once more.
Unbelievable! Neymar's vicious volley denied by Perin. They're still in this. Juve throwing everything at PSG.
Neymar fires a free-kick over from a difficult angle for a right footer. A host of changes coming up.
Galtier readying new signing Carlos Soler to replace Lionel Messi. The Spaniard makes his debut after signing from Valencia. Great spell from Juventus.
Juventus pushing! The crosses are causing havoc for PSG, with Donnarumma denying Locatelli's rebounded cross. Neymar drags an effort wide at the other end.
Galtier making his first changes - defensive ones. Danilo Pereira and Nordi Mukiele replace Vitinha and Achraf Hakimi in straight swaps.
Yellow card for Danilo. Far too tight on Kylian Mbappe, and puts his hand out. A very small touch sends the starboy sprawling. De Scliglio replaces Cuadrado for Juve.
Juventus holding on! Messi has a long-range effort denied by Perin. They're looking to stay in this, to keep it at 2-1 and go all-out in the dying embers.
Close! Mbappe again, linking up with Neymar and Messi, drags just wide. They feel impossible to stop.
The tide has turned in the Old Lady's favour, here. A real sense of belief has been instilled by Max Allegri.