Barcelona host Valencia in an early-season showdown at the Nou Camp, and here is how to watch it LIVE.
The Catalan giants are desperate to stay in touch with leaders Atletico Madrid after a rocky start to the new campaign.
Here is how to watch all the action LIVE in the United Kingdom.
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What time is kick-off?
The game will begin at 8pm UK time on Saturday.
Spain is one hour ahead of British time, meaning a 9pm local time kick-off for the players in Barcelona.
What TV channel is it on?
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Premier 1 will show the action LIVE in the United Kingdom on Saturday - available on Sky channel 412.
Viewers can also stream the action online at www.premierplayer.com.
The first three weeks of the season were shown LIVE on ITV4 in the United Kingdom before Premier Sports and La Liga this week agreed a three-year deal.
Premier Sports will show games across Premier 1, Premier 2 and will be creating a dedicated La Liga TV channel from January.
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What has happened in La Liga so far?
Atletico Madrid have the only perfect record in the Spanish league after three games with Athletic Bilbao and Sevilla both picking up seven points so far.
Real Madrid have only beaten Celta Vigo to date, and been held to draws by Valladolid and Villarreal.
Barcelona, meanwhile, are one point worse off at this stage after their opening-day defeat at Athletic Bilbao.
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The Catalans bounced back to beat Real Betis 5-2 but were held to a 2-2 draw by Osasuna last time out.
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